Tscc transgranular stress corrosion cracking acronymattic. Stress corrosion cracking scc of pipeline steels in nearneutral ph environments has remained a significant integrity risk for oil and gas pipelines. The scc cracks are those cracks which are induced due to. This investigation was initiated to provide governing equations for crack initiation, crack growth, and service life prediction of pipeline steels in nearneutral ph nnph environments. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Near neutral ph stress corrosion cracking of pipelines. Another example is that hydrogen may contact the internal surface of pipes.
Managaing nearneutral ph scc 4 of 158 3rd edition, may 2015 term definition collapse limit plastic collapse limit the maximum stress, strain or load which may be applied prior to onset of plastic collapse. Nearneutral ph stress corrosion cracking of pipelines high ph stress corrosion cracking of pipelines stress corrosion cracking of pipelines in acidic soil environments stress corrosion cracking at pipeline welds stress corrosion cracking of highstrength pipeline steels the final chapter is dedicated to. Li yan, jeanphilippe gravel, jidong kang, luyao xu, muhammad arafin, occurrence of nearneutral ph stress corrosion cracking in x80 and x100 pipe steels under various cathodic protection conditions, corrosion. Luo department of chemical and materials engineering, university of alberta, edmonton, alberta t6g 2g6, canada abstract the roles of dissolved hydrogen in material and anodic dissolution in the nearneutral ph stress corrosion cracking scc process of a pipeline steel was investigated. Two types of pipeline scc modes have been identified based on the environment developed under disbonded coating, i. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Scc in pipelines is further characterized as high ph scc or nearneutral ph scc. Cheng has provided an important service by writing this book, delivering a valuable source of knowledge and information on technologies for managing stress corrosion cracking and enhancing pipeline integrity. It has been found that low ph scc occurs in environments with a low concentration of carbonic acid and bicarbonate ions with the presence of other species, including chloride, sulfate and nitrate ions. Mineral acids like hydrochloric and sulfuric acids are most widely used in pickling. Pitting and cracking occurrence article in acta materialia 551 january 2007 with 55 reads. Nearneutral ph scc a form of scc on underground pipelines associated with a nearneutral ph electrolyte in which the crack growth or crack path is through or across the grains of a metal. Corrosion inhibitors have been frequently studied, since they offer simple solution for protection of metals against corrosion in aqueous environment.
The new definition provides criteria for determining when a. In this article, the impact of plastic prestrain on nearneutral ph stress corrosion cracking scc susceptibility of welded x70 steel was investigated with a slow strain rate tensile ssrt test. Occurrence of nearneutral ph stress corrosion cracking in. Cepa recommended practices for managing near neutral ph. In the case of near neutral ph scc, the cracking environment. Stress corrosion cracking, underground pipeline, pressure fluctuation, hydrostatic testing, nearneutral ph overview currently, there is a poor understanding of the effects of pressure related parameters operating pressure, pressure fluctuations, and hydrostatic testings on external stress corrosion crack propagation in pipelines in. The exposure conditions involved hydrocarbon fluids following an initial hydrotest. Abstract the application of strainbased design for pipelines requires comprehensive understanding of the postyield mechanical behavior of materials. In the case of near neutralph scc, the cracking environment appears to be a diluted groundwater containing dissolved co 2. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. When the local stress level at the crack tip is smaller than this value, corrosion, rather than cracking, occurs inside the crack. This paper is aimed at providing an overview of stress corrosion cracking scc of pipeline steels exposed to nearneutral ph environments and corresponding integrity strategies being developed based on the understanding of the. When cyclic loading was applied in the stress corrosion cracking initiation tests, based. Investigating the mechanism of transgranular stress corrosion cracking in near neutral ph environments on buried fuel transmission pipelines nevertheless, these materials suffer from transgranular stress corrosion cracking tscc, that occurs by environmentallyinduced.
Delanty, transgranular stress corrosion cracking of high pressure pipelines in contact with solutions of near neutral ph, corrosion 50 1994 394408. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Highph and nearneutral ph scc of pipelines rosen group. Investigating the mechanism of stress corrosion cracking.
Also, the environment at the bottom of a pit will become more acidic. Although no stainless steel grade is totally immune. Nearneutral ph stress corrosion cracking of pipelines. It has been found that low ph scc occurs in environments with a low concentration of. Luo department of chemical and materials engineering, university of alberta, edmonton, alberta t6g 2g6, canada abstract the roles of dissolved hydrogen in material and anodic dissolution in the near neutral ph stress corrosion cracking scc process of a pipeline steel was investigated. Stress corrosion cracking initiation under the disbonded. Nearneutral ph scc ph 68 occurs by transgranular cracking where corrosion. Pdf stress corrosion cracking of pipelines alexander. Stress corrosion cracking of natural gas pipelines in low ph environments is a serious problem for the gas transmission industry. The results revealed that at nearneutral ph condition the anodic dissolution at crack tip was the dominant mechanism. Pipeline stress corrosion cracking scc corrosion doctors. Chloride stress corrosion cracking in austenitic stainless. This paper describes results of an ongoing research program investigating crack growth of api x65 and x52 line pipe steels in a low ph cracking environment using a jintegral technique.
Bahalaou, horeh, investigating the mechanism of stress corrosion cracking in nearneutral and high ph environments for api, 5l x52 steel, corros. While there is general agreement on a role for hydrogen in th. Mechanisms of highph and nearneutralph scc of underground. Chloride stress corrosion cracking in austenitic stainless steel. Nearneutral ph stress corrosion cracking nonclassic type a nearneutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. Investigating the mechanism of transgranular stress corrosion cracking in nearneutral ph environments on buried fuel transmission pipelines nevertheless, these materials suffer from transgranular stress corrosion cracking tscc, that occurs by environmentallyinduced. Cepa recommended practices for managing near neutral. An overview of nearneutral ph stress corrosion cracking in. Abstract nearneutralph scc has been one of the major remaining.
Stress corrosion cracking of pipelines begins with a brief introduction and then explores general principals of stress corrosion cracking, including two detailed case studies of pipeline failure. Crack growth behavior of pipeline steels under variable. Stress corrosion cracking of pipelines electrochemistry. It is defined as the negative log base 10 of the hydrogen ion. Initiation and inhibition of corrosion cracking process. Stress corrosion cracking is the growth of crack formation in a corrosive environment. Cheng, mechanistic investigation of hydrogenenhanced anodic dissolution of x70 pipe steel and its implication on nearneutral ph scc. These soils were collected from pipeline sites where near neutral ph scc has been observed. The severity of four different soil environments toward the development of near neutral ph stress corrosion cracking scc of pipeline steel was evaluated using slow strainrate testing ssrt. The application of strainbased design for pipelines requires comprehensive understanding of the postyield mechanical behavior of materials. Colony an area of stress corrosion cracks occurring in groups of a few to thousands of cracks within a relatively. The role of residual stress in neutral ph stress corrosion cracking of pipeline steels. This research aims at understanding the crack propagation behavior of pipeline steels under variable pressure fluctuations in a nearneutral ph environment. As such, the newly discovered form of scc is equally referred to as transgranular scc or near neutral ph scc.
The source of the co 2 is typically the decay of organic matter and geochemical reactions in the soil. Boven, transgranular crack growth in the pipeline steels exposed to near neutral ph soil aqueous solutions. If inspection tools dont exist diameter or piggability an appropriately defined. Sulfur corrosion products were found in the pits and sulfate reducing bacteria were suspected resulting from prolonged exposure to hydrotest water. The analysis of the influence of various factors on the development of stress corrosion defects in the main gas pipeline walls in the conditions of the european part of the russian. Environmental aspects of nearneutral ph stress corrosion. In the liquid nprm, phmsa proposed to add a new definition of significant stress corrosion cracking. Stress corrosion cracking, underground pipeline, pressure fluctuation, hydrostatic testing, near neutral ph overview currently, there is a poor understanding of the effects of pressure related parameters operating pressure, pressure fluctuations, and hydrostatic testings on external stress corrosion crack propagation in pipelines in. Stress corrosion cracking scc causes sudden failure of metals and other materials subjected to stress in a corrosive environment, especially at elevated temperatures.
Inhibition is a preventive measure against corrosive attack on metallic materials. Marshakov, stress corrosion cracking of pipeline steel in near neutral ph environment, in proceedings of materials science technology, pittsburgh, pa, usa, 2014. Near neutral ph stress corrosion cracking nonclassic type a near neutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. The analysis of the influence of various factors on the development of stress corrosion defects in the main gas pipeline walls in the conditions of the european part of the russian federation. Extensive field investigations have shown that nnphscc is characterized by wide transgranular cracks 1, 2, and usually occurs in dilute near neutral ph. Occurrence of stress corrosion cracking of pipelines under a nearneutral ph condition depends on the synergism of stress, hydrogen and anodic dissolution at the crack tip of the steel. Stress corrosion cracking article about stress corrosion. Stress corrosion cracking of pipelines y frank cheng. The new definition provides criteria for determining when a probable crack defect in a pipeline segment must be excavated and repaired. The earliest cracks to appear initiated at corrosion pits that formed around nonmetallic inclusions, and later cracks grew from corrosion p its that formed randomly on the surface. Near neutral ph stress corrosion crack initiaion under simulated coating disbondment. Stress on nearneutral ph scc found by excavation dataset 30 table 21 distribution of nearneutral ph stress corrosion crack depths and lengths found by. Pdf stress corrosion cracking of pipeline steel in near. Table 19 effect of pipeline age on nearneutral ph scc found by excavation dataset 30 table 20 effect of op.
Transgranular article about transgranular by the free. Some other studies on stress corrosion cracking of x52 steel rebak et al. Characteristics of nearneutralph stress corrosion cracks in an x. Abstract nearneutral also termed low ph transgranular cracking of line pipe steels has been recognized as distinct from socalled highph or classical pipeline scc since the mid1980s. Characteristics of nearneutralph stress corrosion cracks. Pdf corrosion fatigue and nearneutral ph stress corrosion. In the case of near neutralph scc, the cracking environment appears to be a.
Effect of co2 on nearneutral ph stress corrosion cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The two patches can be characterized as containing e. This research is aimed at understanding near neutral ph scc initiation under disbonded coatings of pipeline steels, and the effect of different environmental and operational factors on crack initiation. Abstract two patches of nearneutralph stress corrosion cracks scc, as developed on a pipeline steel during service, have been characterized. The localized pitting corrosion was produced in aluminum floats on a storage tank roof. This book is divided into three parts looking at the mechanisms of stress corrosion cracking. Scc does not occur as a result of stress at pipe surface with flaws caused by corrosion, though concentration of stress does take place at such areas.
The demand for pipeline steels has increased in the last several decades since they were able to provide an immune and economical way to carry oil and natural gas over long distances. Stress on near neutral ph scc found by excavation dataset 30 table 21 distribution of near neutral ph stress corrosion crack depths and lengths found by. Nearneutral ph scc this type of transgranular cracking mode of scc was. When the stress level at the crack tip is sufficiently high to exceed the stress associated with the applied load of 600 n, corrosion becomes less important in the cracking process. One of the outstanding problems in understanding near neutral ph stress corrosion cracking nnphscc in pipelines is the determination of the factors that cause a very small number of the cracks.
The program, which has two tracksa field track and an engineering track, emphasizes technology, industry standards. This mode of attack is termed stress corrosion cracking scc. Crack growth behavior of pipeline steels under variable pressure fluctuations in a nearneutral ph environment by. Parkins used to refer to a stress corrosion spectrum that had scc of highstrength steel at.
In order to identify the mechanism contributes in stress corrosion cracking. Significant stress corrosion crackingmeans a stress corrosion cracking scc. Stress corrosion cracking scc is a slow cracking process induced in metallic alloy pipelines by mechanical stress due to loading and the presence of a corrosive environment. Stress enhanced corrosion at the tip of nearneutral ph. No matter how well these pipelines are designed, constructed and protected, once in place they are subjected to environmental abuse, external damage, coating disbondments, inherent mill defects, soil movementsinstability and third party damage. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Causes of stress corrosion cracking in pipelines ducorr. Material selection for sour service environment pipeline.
Although it has traditionally been termed stress corrosion cracking, crack growth has never been observed under a static loading condition. Stress corrosion cracking on canadian oil and gas pipelinesscc scc scc scc scc scc scc. Nnscc near neutral stress corrosion cracking acronymattic. An overview of nearneutral ph stress corrosion cracking. Hydrogen environment assisted cracking of a modern ultrahigh strength martensitic stainless steel greger l. Boven, transgranular crack growth in the pipeline steels exposed to nearneutral ph soil aqueous solutions.
Lowph stress corrosion cracking of natural gas pipelines. The problem affects industries such as petrochemical and nuclear power production. There are two important damage modes in pipeline steels including stress corrosion cracking scc and hydrogen induced cracking hic. Near neutral ph stress corrosion cracking nnphscc has been an integrity risk for oil and gas pipelines for more than two decades. Characterization of crack tip electrochemistry using a. The chemical environment that causes scc for a given alloy is often one which is only mildly corrosive to the metal. External stress corrosion cracking scc continues to be an integrity concern for the natural gas pipeline industry. However, stress corrosion cracking scc has been recognized as one of potential threats to the safe operation of pipelines 2, 3, 4. Near neutral ph stress corrosion cracking of pipelines high ph stress corrosion cracking of pipelines stress corrosion cracking of pipelines in acidic soil environments stress corrosion cracking at pipeline welds stress corrosion cracking of highstrength pipeline steels the final chapter is dedicated to. Stress corrosion cracking of natural gas pipelines in lowph environments is a serious problem for the gas transmission industry.
The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Table 19 effect of pipeline age on near neutral ph scc found by excavation dataset 30 table 20 effect of op. The role of residual stress in neutral ph stress corrosion. This research is aimed at understanding nearneutral ph scc initiation under disbonded coatings of pipeline steels, and the effect of different environmental and operational factors on crack initiation. These recommended practices represent an overview of the methods used. Pioszak department of materials science and engineering, center for electrochemical science and engineering, university of virginia, 395 mccormick road, p. Typically this form of cracking has limited branching and is associated with some corrosion of the crack walls and sometimes of the pipe surface. What causes stress corrosion cracking in pipelines. Initiating nearneutral ph scc in the laboratory under stressing conditions that are representative of those on an operating gas pipeline has proven very difficult. Nearneutral ph stress corrosion crack initiaion under simulated coating disbondment. This paper describes results of an ongoing research program investigating crack growth of api x65 and x52 line pipe steels in a lowph cracking environment using a jintegral technique. Nearneutral ph stress corrosion cracking susceptibility. Since the first report of transgranular cracking, a number of similar pipeline failures have been reported around the world. Cepa recommended practices for managaing nearneutral ph scc 1 of 158 3rd edition, may 2015 executive summary this 3rd stedition of the cepa recommended practices for stress corrosion cracking builds on the 1 and 2nd editions published in 1999 and 2007, respectively.
Corrosion fatigue and nearneutral ph stress corrosion. For example, in most initiation tests the environment surrounding the pipe was. A mechanistic study on nearneutral ph stress corrosion. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Highph scc failures of underground pipelines have occurred in a wide variety of. Effects of o2 and co2 on nearneutralph and stress corrosion.
A mechanistic study on near neutral ph stress corrosion cracking of pipeline steel b. The scc cracks are those cracks which are induced due to the combined effects. The combination of tensile stress and a specific corrosive environment can crack stainless steels. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Note that the ph here refers to the environment on the pipe surface at the crack location, not the ph of the soil itself. Stress corrosion cracks in pipeline steels encyclopedia. The pitting occurred in the absence of chlorides at a near neutral ph where aluminum would be expected to exhibit good resistance to corrosion. Corrosion is a natural process driven by energy consideration. Nearneutral also termed low ph transgranular cracking of line pipe steels has been recognized as distinct from socalled highph or classical pipeline scc. Mechanistic aspect of nearneutral ph stress corrosion.